Radium isotopes in the Ulsan Bay.

In order to estimate the fluxes of Ra isotopes, we measured 224Ra, 226Ra, and 228Ra activities in the Ulsan Bay mixing zone. The convex upwards curvature of the plot of Ra isotope activities versus salinity for the mixing zone suggests that Ra isotopes are supplied from particles entering the mixing zone from both the river and bottom sediments. This addition increases the estuarine flux of 226Ra and 228Ra to the outer sea by factors of 15 and 95 over the flux attributable to Ra dissolved in the riverine water alone. In order to estimate the residence time of the water in Ulsan Bay, we applied a mass balance model to the distribution of 224Ra and 226Ra activities in the Ulsan Bay mixing zone with the inflow from the Taehwa River. The obtained residence times of the waters in the Ulsan Bay were estimated to be 6.8-11.4 d. The waters in the upper part of the estuary have long residence times whereas those in the lower part, in contact with the open sea, have shorter residence times. The mean residence time of the water in the Ulsan Bay was estimated to be 9.1 d.